盛桦 研究员

           中国科学院化学研究所

           光化学院重点实验室

           办公室：6号楼1416

          e-mail：hsheng@iccas.ac.cn

个人经历

2023年中科院"百人计划"终期评估优秀

2022年获基金委优秀青年基金项目资助

2018年入选国家高层次引进人才青年项目

2024.7 ~ 至今          中国科学院化学研究所  研究员

2018.9 ~ 2024.7       中国科学院化学研究所  项目研究员

2014.10 ~ 2018.5     劳伦斯伯克利国家实验室(LBNL)  博士后

2008.9 ~ 2014.7       中国科学院化学研究所  硕博连读

2004.9 ~ 2008.7       中国科学技术大学  本科0419

2025-2026年度招收硕博生1名，专业方向为环境催化，人工光合成，欢迎化学、材料学、环境科学等相关专业背景的同学联系保送或报考本课题组。

博士三年级：赵琪

博士二年级：黄星妙 张志勇

博士一年级：张博洋

硕士二年级：杨娜

硕士一年级：赵谨瑜

已毕业/出站：

热沙来提·海里里：北京工业大学

王伟：中科院北京纳米能源与系统研究所

谢士杰：大连理工大学

盛波：淮阴工学院

李杨凡：山西师范大学

张晚依：中石化经济技术研究院

谢杨恩：长鑫存储

黄庆：长鑫存储

环境光/电催化

1. CO₂的捕集和光/电催化转化：尤其聚焦于环境中的CO₂（如烟道气、空气等）的直接转化利用，实现对低浓度CO₂的富集和在有氧条件下的选择性还原，进一步结合氮循环过程（硝酸盐和氨的转化）实现CO₂向高附加值碳-氮偶联化学品（如尿素、甲酰胺等）的转化。

2. 水-气界面上的协同光催化反应：光催化直接依赖太阳光能供能，因此在开放环境中是一个自驱动、可持续的反应体系。由此构建漂浮式的光催化反应器件，可应用于环境水体的原位净化；通过进一步实现氧化和还原过程的宏观空间分离，可以实现水-气协同反应的双功能光催化过程。

3. 原位红外光谱系统的搭建和方法学发展：通过发展契合表面反应时间尺度（毫秒~秒）、多检测模式的红外光谱仪器和方法学，揭示光/电催化反应过程的微观机制。

1. 国家级青年人才, 2019.2-2022.2, 主持 

2. 中科院化学所创新培育项目，"CO₂深度还原机理的快速扫描红外光谱研究"，2020.1-2023.12，主持

3. 基金委面上项目，"基于新型电子/质子传递膜的双功能的光催化降解污染物体系"，No.22076193, 2021.1-2024.12，主持

4. 国家重点研发计划"变革性技术关键科学问题"，"面向地外原位资源利用技术的人工光合成关键材料与系统研究"，No.2020YFA0710303, 2020.12-2025.11，课题骨干

5. 中国科学院稳定支持基础研究领域青年团队计划， "高效光解水中的科学问题-光解水过程全时空域原位动态成像研究"，No.YSBR-004, 2021.6-2026.6，课题骨干

6. 基金委优秀青年基金项目，"环境光催化"，No.22222609，2023.1-2025.12，主持

7. 基金委创新研究群体项目，"污染物光催化降解和界面光化学转化"，No.22321004， 2024.1-2028.12，课题骨干

32. Jinjie Hao, Xingmiao Huang, Yangfan Li, Qi Zhao, Baipeng Yin, Qing-Yuan Meng, Jincai Zhao, Jinnian Yao, Hua Sheng* and Chuang Zhang*, "Spin Catalysis of Urea Electrosynthesis Using Diluted Magnetic Oxides", CCS Chem. DOI: 10.31635/ccschem.025.202506003

31. Zhiyong Zhang(张志勇) , Qing Huang, Yangen Xie, Boyang Zhang, Qi Zhao, Xingmiao Huang, Na Yang, Hongwei Ji, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Solar-Driven Direct Coupling of Atmospheric CO₂ with Ammonia for Urea Synthesis", Nat. Commun. 2025, 16, 10493. (★Featured on Nature Communications Editors’ Highlights webpage for "Materials Science and Chemistry")

30. Qi Zhao^#(赵琪), Qiang Huang^#, Ran Duan, Zhiyong Zhang, Yangen Xie, Wenjing Song, Hua Sheng* and Jincai Zhao, "Dynamic Identification of Reactive Iron-Oxo Species in Heterogeneous Fenton-like Reaction via Operando Stopped-Flow IR Spectroscopy", Nat. Commun. 2025, 16, 9227.

29. Bo Sheng*(盛波), Xingmiao Huang, Qi Zhao, Zhiyong Zhang, Ran Duan, Jing Zhang, Chuncheng Chen, Jincai Zhao and Hua Sheng*, "Discriminative Peroxymonosulfate Activation on Iron Carbides for Redox-Neutral Singlet Oxygen Generation", Angew. Chem. Int. Ed., 2025, 64(50), e202519774. (★Selected as “Hot Paper” by Editor)

28. Xingmiao Huang^#(黄星妙), Shijie Xie^#(谢士杰), Bo Sheng, Bowen Xiao, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Air-Level Oxygen Enables 100% Selectivity in Urea Synthesis via Photocatalytic C-N Coupling of CO and Ammonia", Angew. Chem. Int. Ed. 2025, 64, e202505630. (★Selected as "Hot Paper" by Editor)

27. Zhiyong Zhang(张志勇), Yang Wang, Yangen Xie, Toru Tsukamoto, Qi Zhao, Qing Huang, Xingmiao Huang, Boyang Zhang, Wenjing Song, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Floatable Artificial Leaf to Couple Oxygen-Tolerant CO₂ Conversion with Water Purification", Nat. Commun. 2025, 16, 274. (★ESI Highly Cited Paper)

26. Yangfan Li(李杨凡), Xingmiao Huang, Boyang Zhang, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Mixed CO Adsorption Modes Induced by Lattice Strain to Facilitate C-C Coupling during Electrochemical CO Reduction", Appl. Catal. B-Environ. Energy 2025, 361, 124627.

25. Wanyi Zhang^#(张晚依), Chaoyuan Deng^#, Wei Wang*(王伟), Hua Sheng* and Jincai Zhao, "Achieving Almost 100% Selectivity in Photocatalytic CO₂ Reduction to Methane via In-situ Atmosphere Regulation Strategy", Adv. Mater. 2024, 36(35), 2405825.

24. Reshalaiti Hailili*(热沙来提•海里里), Zelong Li, Xu Lu, Hua Sheng*, Detlef W. Bahnemann and Jincai Zhao, "Ultrathin Defective Heterojunction for Visible Light NO Removal: Correlation between Microstructure and Reaction Mechanism", Environ. Sci.-Nano, 2024, 11(8), 3301-3316. (★Selected as Inside Cover)

23. Yangen Xie(谢杨恩), Min Wang, Qiang Huang, Qing Huang, Bo Sheng, Wenjing Song, Hua Sheng* and Jincai Zhao, "A Floatable Photocatalyst to Synergistically Promote CO₂ Reduction and Water Oxidation by Creating Oriented Charge Separation across a Tri-phase Interface", Energy Environ. Sci. 2024, 17(7), 4725-4734.

22. Baipeng Yin, Can Wang, Shijie Xie, Jianmin Gu, Hua Sheng*, De-Xian Wang*, Jiannian Yao and Chuang Zhang*, "Regulating Spin Density Using TEMPOL Molecules for Enhanced CO₂-to-Ethylene Conversion by HKUST-1 Framework Derived Electrocatalysts", Angew. Chem. Int. Ed. 2024, 63(29), e202405873. 

21. Xingmiao Huang(黄星妙), Yangfan Li, Shijie Xie*(谢士杰), Qi Zhao, Boyang Zhang, Zhiyong Zhang, Hua Sheng* and Jincai Zhao, "The Tandem Nitrate and CO₂ Reduction for Urea Electrosynthesis: Role of Surface N-Intermediates in CO₂ Capture and Activation", Angew. Chem. Int. Ed. 2024, 63(24), e202403980. (★ESI Highly Cited Paper)

20. Qing Huang(黄庆) and Hua Sheng*, "Magnetic-Field-Induced Spin Regulation in Electrocatalytic Reactions", Chem. Eur. J. 2024, 30(17), e202400352. (Invited Review)

19. Wei Wang^#(王伟), Wanyi Zhang^#(张晚依), Chaoyuan Deng, Hua Sheng* and Jincai Zhao, "Accelerated Photocatalytic Carbon Dioxide Reduction and Water Oxidation under Spatial Synergy", Angew. Chem. Int. Ed. 2024, 63(7), e202317969. (★ESI Highly Cited Paper)

18. Bo Sheng(盛波), Yangen Xie, Qi Zhao, Hua Sheng* and Jincai Zhao, "Proton Reservoir in Polymer Photocatalysts for the Superior H₂O₂ Photosynthesis", Energy Environ. Sci. 2023, 16(10), 4612-4619.

17. Zhong-Ting Hu^#, Yan-Fei Fei^#, Qiong-Yu Wang, Qi Zhao, Siew-Leng Loo, Mian Hu, Yonghe Li, Yujie Song, Jie-Xin Wang, Zhi-Gang Shen, Hua Sheng*, Jiade Wang* and Jincai Zhao, "Catalytic Disinfection: Quasi-Dynamically Monitoring Bacteria Sterilization Based on CuNPs/ZnIn₂S₄ Disinfectants and in-situ CuNPs Regeneration", Appl. Catal. B-Environ. 2023, 337, 122995.

16. Qing Huang^#(黄庆), Shijie Xie^#(谢士杰), Jinjie Hao, Zijing Ding*, Chuang Zhang*, Hua Sheng* and Jincai Zhao, "Spin-Enhanced O-H Cleavage in Electrochemical Water Oxidation", Angew. Chem. Int. Ed. 2023, 62(20), e202300469. (Hot Paper)

15. Yangfan Li^#(李杨凡), Shijie Xie^#(谢士杰), Xingmiao Huang, Wenjing Song, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Spectating the Proton Migration on Catalyst with Noninnocent Ligand in Aqueous Electrochemical CO₂ Reduction", Appl. Catal. B-Environ. 2023, 329, 122542.

14. Shijie Xie^#(谢士杰), Chaoyuan Deng^#, Qing Huang, Chuang Zhang*, Chuncheng Chen, Jincai Zhao* and Hua Sheng*, "Facilitated Photocatalytic CO₂ Reduction in Aerobic Environment on a Copper-Porphyrin Metal-Organic Framework", Angew. Chem. Int. Ed. 2023, 62(10), e202216717. (★Top Viewed Article in Angew. Chem. Int. Ed.) (★ESI Highly Cited Paper)

Introducing...Hua Sheng, Angew. Chem. Int. Ed. 2023, 62(13), e202301138. 

13. Jinjie Hao, Shijie Xie, Qing Huang, Zijing Ding, Hua Sheng*, Chuang Zhang* and Jiannian Yao, "Spin-Enhanced C-C Coupling in CO₂ Electroreduction with Oxide-Derived Copper", CCS Chem. 2023, 5(9), 2046-2058.

12. Bo Sheng^#(盛波), Chaoyuan Deng^#, Yangfan Li, Shijie Xie, Zhaohui Wang*, Hua Sheng* and Jincai Zhao, "In-Situ Hydroxylation of Single-Atom Iron Catalyst for Preferential ¹O₂ Production from H₂O₂", ACS Catal. 2022, 12(23), 14679-14688.

11. Reshalaiti Hailili*(热沙来提•海里里), Hongwei Ji, Kaiwen Wang, Xing'an Dong, Chuncheng Chen, Hua Sheng*, Detlef W. Bahnemann* and Jincai Zhao, "ZnO with Controllable Oxygen Vacancies for Photocatalytic Nitrogen Oxide Removal", ACS Catal. 2022, 12(16), 10004-10017. (★ESI Highly Cited Paper)

10. Shijie Xie^#(谢士杰), Yangfan Li^#(李杨凡), Bo Sheng, Wanyi Zhang, Wei Wang, Chuncheng Chen, Jikun Li*, Hua Sheng* and Jincai Zhao, "Self-Reconstruction of Paddle-Wheel Copper-Node to Facilitate the Photocatalytic CO₂ Reduction to Ethane", Appl. Catal. B-Environ. 2022, 310, 121320.

9. Reshalaiti Hailili^#(热沙来提•海里里), Zhi-Qiang Wang^#, Hongwei Ji, Chuncheng Chen, Xue-Qing Gong*, Hua Sheng* and Jincai Zhao, "Mechanistic Insights into the Photocatalytic Reduction of Nitric Oxide to Nitrogen on Oxygen-Deficient Quasi-Two-Dimensional Bismuth-Based Perovskites", Environ. Sci.-Nano 2022, 9(4), 1453-1465.

8. Wei Wang(王伟), Chaoyuan Deng, Shijie Xie, Yangfan Li, Wanyi Zhang, Hua Sheng*, Chuncheng Chen and Jincai Zhao, "Photocatalytic C-C Coupling from Carbon Dioxide Reduction on Copper Oxide with Mixed-Valence Copper(I)/Copper(II)", J. Am. Chem. Soc. 2021, 143(7), 2984-2993. (★Most Cited Publication in JACS from 2020-2021) (★ESI Highly Cited Paper, Hot Paper)

7. Hongna Zhang, Yangfan Li, Jinzhao Wang, Ningning Wu, Hua Sheng*, Chuncheng Chen* and Jincai Zhao, "An Unprecedent Hydride Transfer Pathway for Selective Photocatalytic Reduction of CO₂ to Formic Acid on TiO₂", Appl. Catal. B-Environ. 2021, 284, 119692. 

6. Jose A. Corgejo^#, Hua Sheng^#, Eran Edri^#, Caroline M. Ajo-Franklin* and Heinz Frei*, "Nanoscale Membranes that Chemically Isolate and Electronically Wire Up the Abiotic/Biotic Interface", Nat. Commun. 2018, 9, 2263.

5. Hua Sheng, Myoung Hwan Oh, Wojciech T. Osowiecki, Wooyul Kim, A. Paul Alivisatos and Heinz Frei*, "Carbon Dioxide Dimer Radical Anion as Surface Intermediate of Photoinduced CO₂ Reduction at Aqueous Cu and CdSe Nanoparticle Catalysts by Rapid-Scan FT-IR Spectroscopy", J. Am. Chem. Soc. 2018, 140(12), 4363-4371.

Highlighted: "Dimers on the Way", by Davide Esposito, Nat. Catal. 2018, 1, 234.

4. Hua Sheng and Heinz Frei*, "Direct Observation by Rapid-Scan FT-IR Spectroscopy of Two-Electron-Reduced Intermediate of Tetraza Catalyst [Co^IIN₄H(MeCN)]²⁺ Converting CO₂ to CO", J. Am. Chem. Soc. 2016, 138(31), 9959-9967.

3. Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen* and Jincai Zhao, "Activation of Water in Titanium Dioxide Photocatalysis by Formation of Surface Hydrogen Bonds: An In Situ IR Spectroscopy Study", Angew. Chem. Int. Ed. 2015, 54(20), 5905-5909.

2. Hua Sheng, Hongwei Ji, Wanhong Ma, Chuncheng Chen* and Jincai Zhao, "Direct Four-Electron Reduction of O₂ to H₂O on TiO₂ surface by Pendant Proton Relay", Angew. Chem. Int. Ed. 2013, 52(7), 9686-9690.

1. Hua Sheng, Qin Li, Wanhong Ma, Hongwei Ji, Chuncheng Chen* and Jincai Zhao, "Photocatalytic Degradation of Organic Pollutants on Surface Anionized TiO₂: Common Effect of Anions for High Hole-Availability by Water", Appl. Catal. B-Environ. 2013, 138, 212-218.