盛桦 研究员

           中国科学院化学研究所

           光化学院重点实验室

           办公室：6号楼1416

          e-mail：hsheng@iccas.ac.cn

个人经历

2023年中科院"百人计划"终期评估优秀

2022年获基金委优秀青年基金项目资助

2018年入选国家高层次引进人才青年项目

2024.7 ~ 至今          中国科学院化学研究所  研究员

2018.9 ~ 2024.7       中国科学院化学研究所  项目研究员

2014.10 ~ 2018.5     劳伦斯伯克利国家实验室(LBNL)  博士后

2008.9 ~ 2014.7       中国科学院化学研究所  硕博连读

2004.9 ~ 2008.7       中国科学技术大学  本科0419

2025-2026年度招收硕博生1名，专业方向为环境催化，人工光合成，欢迎化学、材料学、环境科学等相关专业背景的同学联系保送或报考本课题组。

博士后：陈瑞敏

博士研究生：

赵琪（2022级博士）

黄星妙（2021级硕博）

张志勇（2023级博士）

张博洋（2022级硕博）

杨娜（2023级硕博）

硕士研究生：

赵瑾瑜（2024级）

胡望成（2025级）

已毕业/出站：

热沙来提·海里里（博士后）：北京工业大学

王伟（2018级博士、博士后）：中国科学院大学

谢士杰（2019级博士）：大连理工大学

盛波（2020级博士）：淮阴工学院

李杨凡（2018级硕博）：山西师范大学

张晚依（2019级硕博）：中石化经济技术研究院

谢杨恩（2021级博士）：长鑫存储

黄庆（2020级硕博）：长鑫存储

环境光/电催化

1. CO₂的捕集和光/电催化转化：尤其聚焦于环境中的CO₂（如烟道气、空气等）的直接转化利用，实现对低浓度CO₂的富集和在有氧条件下的选择性还原，进一步结合氮循环过程（硝酸盐和氨的转化）实现CO₂向高附加值碳-氮偶联化学品（如尿素、甲酰胺等）的转化。

2. 水-气界面上的协同光催化反应：光催化直接依赖太阳光能供能，因此在开放环境中是一个自驱动、可持续的反应体系。由此构建漂浮式的光催化反应器件，可应用于环境水体的原位净化；通过进一步实现氧化和还原过程的宏观空间分离，可以实现水-气协同反应的双功能光催化过程。

3. 原位红外光谱系统的搭建和方法学发展：通过发展契合表面反应时间尺度（毫秒~秒）、多检测模式的红外光谱仪器和方法学，揭示光/电催化反应过程的微观机制。

1. 国家级青年人才, 2019.2-2022.2, 主持 

2. 中科院化学所创新培育项目，"CO₂深度还原机理的快速扫描红外光谱研究"，2020.1-2023.12，主持

3. 基金委面上项目，"基于新型电子/质子传递膜的双功能的光催化降解污染物体系"，No.22076193, 2021.1-2024.12，主持

4. 国家重点研发计划"变革性技术关键科学问题"，"面向地外原位资源利用技术的人工光合成关键材料与系统研究"，No.2020YFA0710303, 2020.12-2025.11，课题骨干

5. 中国科学院稳定支持基础研究领域青年团队计划， "高效光解水中的科学问题-光解水过程全时空域原位动态成像研究"，No.YSBR-004, 2021.6-2026.6，课题骨干

6. 基金委优秀青年基金项目，"环境光催化"，No.22222609，2023.1-2025.12，主持

7. 基金委创新研究群体项目，"污染物光催化降解和界面光化学转化"，No.22321004， 2024.1-2028.12，课题骨干

2026

37. Boyang Zhang, Zhiyong Zhang, Yangfan Li, Xingmiao Huang, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Spatial Confinement Enables CO₂ Activation via a Molecular Redox Mediator for Multicarbon Electrosynthesis", Appl. Catal. B-Environ. Energy 2027, 127286.

36. Yuan Gao, Jiaqi Sun, Pei-Lin Gao, Qi Zhao, Xinyi Yu, Yujie Song, Jun Hu, Dan Wang, Zhi-Gang Shen, Ze-Hai Xu*, Hua Sheng* and Zhong-Ting Hu*, "Overcoming bacterial fouling: Self-cleaning CNTs-PEI/Cu-ZnIn2S4 membranes for sustained water disinfection", Chem. Eng. J. 2026, 545, 179374.

35. Zhiyong Zhang, Tengxin Cao, Ruimin Chen, Boyang Zhang, Jinyu Zhao, Xu Wang, Ming Su, Min Yang, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Engineering Dynamic Heterogeneous-Homogeneous Hybrid Interfaces for Solar-Driven In-situ Water Remediation", Nat. Water 2026, 4(7), 917-928.

34. Xingmiao Huang, Yangfan Li, Shijie Xie*, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Controlled Interruption of Electrochemical Nitrite Reduction for Switchable NH₂OH and Formamide Synthesis", Angew. Chem. Int. Ed. 2026, 65(25), e5328209.

33. Zhiyong Zhang, Hua Sheng* and Jincai Zhao, "Beyond High-Purity CO₂: Material Innovations and Mechanstic Insights for Photocatalytic CO₂ Reduction under Close-to-Realistic Conditions", Adv. Mater. 2026, e00013. (★Invited Review)

32. Jinjie Hao, Xingmiao Huang, Yangfan Li, Qi Zhao, Baipeng Yin, Qing-Yuan Meng, Jincai Zhao, Jinnian Yao, Hua Sheng* and Chuang Zhang*, "Spin Catalysis of Urea Electrosynthesis Using Diluted Magnetic Oxides", CCS Chem. 2026, 8(5), 2447-2460.

2025

31. Zhiyong Zhang, Qing Huang, Yangen Xie, Boyang Zhang, Qi Zhao, Xingmiao Huang, Na Yang, Hongwei Ji, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Solar-Driven Direct Coupling of Atmospheric CO₂ with Ammonia for Urea Synthesis", Nat. Commun. 2025, 16, 10493. (★Featured on Nature Communications Editors’ Highlights webpage for "Materials Science and Chemistry")

30. Qi Zhao^#, Qiang Huang^#, Ran Duan, Zhiyong Zhang, Yangen Xie, Wenjing Song, Hua Sheng* and Jincai Zhao, "Dynamic Identification of Reactive Iron-Oxo Species in Heterogeneous Fenton-like Reaction via Operando Stopped-Flow IR Spectroscopy", Nat. Commun. 2025, 16, 9227.

29. Bo Sheng*, Xingmiao Huang, Qi Zhao, Zhiyong Zhang, Ran Duan, Jing Zhang, Chuncheng Chen, Jincai Zhao and Hua Sheng*, "Discriminative Peroxymonosulfate Activation on Iron Carbides for Redox-Neutral Singlet Oxygen Generation", Angew. Chem. Int. Ed., 2025, 64(50), e202519774. (★Selected as “Hot Paper” by Editor)

28. Xingmiao Huang^#, Shijie Xie^#, Bo Sheng, Bowen Xiao, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Air-Level Oxygen Enables 100% Selectivity in Urea Synthesis via Photocatalytic C-N Coupling of CO and Ammonia", Angew. Chem. Int. Ed. 2025, 64, e202505630. (★Selected as "Hot Paper" by Editor)

27. Zhiyong Zhang, Yang Wang, Yangen Xie, Toru Tsukamoto, Qi Zhao, Qing Huang, Xingmiao Huang, Boyang Zhang, Wenjing Song, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Floatable Artificial Leaf to Couple Oxygen-Tolerant CO₂ Conversion with Water Purification", Nat. Commun. 2025, 16, 274. (★ESI Highly Cited Paper)

26. Yangfan Li, Xingmiao Huang, Boyang Zhang, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Mixed CO Adsorption Modes Induced by Lattice Strain to Facilitate C-C Coupling during Electrochemical CO Reduction", Appl. Catal. B-Environ. Energy 2025, 361, 124627.

25. Wanyi Zhang^#, Chaoyuan Deng^#, Wei Wang*, Hua Sheng* and Jincai Zhao, "Achieving Almost 100% Selectivity in Photocatalytic CO₂ Reduction to Methane via In-situ Atmosphere Regulation Strategy", Adv. Mater. 2024, 36(35), 2405825.

24. Reshalaiti Hailili*, Zelong Li, Xu Lu, Hua Sheng*, Detlef W. Bahnemann and Jincai Zhao, "Ultrathin Defective Heterojunction for Visible Light NO Removal: Correlation between Microstructure and Reaction Mechanism", Environ. Sci.-Nano, 2024, 11(8), 3301-3316. (★Selected as Inside Cover)

23. Yangen Xie, Min Wang, Qiang Huang, Qing Huang, Bo Sheng, Wenjing Song, Hua Sheng* and Jincai Zhao, "A Floatable Photocatalyst to Synergistically Promote CO₂ Reduction and Water Oxidation by Creating Oriented Charge Separation across a Tri-phase Interface", Energy Environ. Sci. 2024, 17(7), 4725-4734.

22. Baipeng Yin, Can Wang, Shijie Xie, Jianmin Gu, Hua Sheng*, De-Xian Wang*, Jiannian Yao and Chuang Zhang*, "Regulating Spin Density Using TEMPOL Molecules for Enhanced CO₂-to-Ethylene Conversion by HKUST-1 Framework Derived Electrocatalysts", Angew. Chem. Int. Ed. 2024, 63(29), e202405873. 

21. Xingmiao Huang, Yangfan Li, Shijie Xie*(谢士杰), Qi Zhao, Boyang Zhang, Zhiyong Zhang, Hua Sheng* and Jincai Zhao, "The Tandem Nitrate and CO₂ Reduction for Urea Electrosynthesis: Role of Surface N-Intermediates in CO₂ Capture and Activation", Angew. Chem. Int. Ed. 2024, 63(24), e202403980. (★ESI Highly Cited Paper)

20. Qing Huang and Hua Sheng*, "Magnetic-Field-Induced Spin Regulation in Electrocatalytic Reactions", Chem. Eur. J. 2024, 30(17), e202400352. (Invited Review)

19. Wei Wang^#, Wanyi Zhang^#, Chaoyuan Deng, Hua Sheng* and Jincai Zhao, "Accelerated Photocatalytic Carbon Dioxide Reduction and Water Oxidation under Spatial Synergy", Angew. Chem. Int. Ed. 2024, 63(7), e202317969. (★ESI Highly Cited Paper)

18. Bo Sheng, Yangen Xie, Qi Zhao, Hua Sheng* and Jincai Zhao, "Proton Reservoir in Polymer Photocatalysts for the Superior H₂O₂ Photosynthesis", Energy Environ. Sci. 2023, 16(10), 4612-4619.

17. Zhong-Ting Hu^#, Yan-Fei Fei^#, Qiong-Yu Wang, Qi Zhao, Siew-Leng Loo, Mian Hu, Yonghe Li, Yujie Song, Jie-Xin Wang, Zhi-Gang Shen, Hua Sheng*, Jiade Wang* and Jincai Zhao, "Catalytic Disinfection: Quasi-Dynamically Monitoring Bacteria Sterilization Based on CuNPs/ZnIn₂S₄ Disinfectants and in-situ CuNPs Regeneration", Appl. Catal. B-Environ. 2023, 337, 122995.

16. Qing Huang^#, Shijie Xie^#, Jinjie Hao, Zijing Ding*, Chuang Zhang*, Hua Sheng* and Jincai Zhao, "Spin-Enhanced O-H Cleavage in Electrochemical Water Oxidation", Angew. Chem. Int. Ed. 2023, 62(20), e202300469. (Hot Paper)

15. Yangfan Li^#, Shijie Xie^#, Xingmiao Huang, Wenjing Song, Chuncheng Chen, Hua Sheng* and Jincai Zhao, "Spectating the Proton Migration on Catalyst with Noninnocent Ligand in Aqueous Electrochemical CO₂ Reduction", Appl. Catal. B-Environ. 2023, 329, 122542.

14. Shijie Xie^#, Chaoyuan Deng^#, Qing Huang, Chuang Zhang*, Chuncheng Chen, Jincai Zhao* and Hua Sheng*, "Facilitated Photocatalytic CO₂ Reduction in Aerobic Environment on a Copper-Porphyrin Metal-Organic Framework", Angew. Chem. Int. Ed. 2023, 62(10), e202216717. (★Top Viewed Article in Angew. Chem. Int. Ed.) (★ESI Highly Cited Paper)

Introducing...Hua Sheng, Angew. Chem. Int. Ed. 2023, 62(13), e202301138. 

13. Jinjie Hao, Shijie Xie, Qing Huang, Zijing Ding, Hua Sheng*, Chuang Zhang* and Jiannian Yao, "Spin-Enhanced C-C Coupling in CO₂ Electroreduction with Oxide-Derived Copper", CCS Chem. 2023, 5(9), 2046-2058.

12. Bo Sheng^#, Chaoyuan Deng^#, Yangfan Li, Shijie Xie, Zhaohui Wang*, Hua Sheng* and Jincai Zhao, "In-Situ Hydroxylation of Single-Atom Iron Catalyst for Preferential ¹O₂ Production from H₂O₂", ACS Catal. 2022, 12(23), 14679-14688.

11. Reshalaiti Hailili*, Hongwei Ji, Kaiwen Wang, Xing'an Dong, Chuncheng Chen, Hua Sheng*, Detlef W. Bahnemann* and Jincai Zhao, "ZnO with Controllable Oxygen Vacancies for Photocatalytic Nitrogen Oxide Removal", ACS Catal. 2022, 12(16), 10004-10017. (★ESI Highly Cited Paper)

10. Shijie Xie^#, Yangfan Li^#, Bo Sheng, Wanyi Zhang, Wei Wang, Chuncheng Chen, Jikun Li*, Hua Sheng* and Jincai Zhao, "Self-Reconstruction of Paddle-Wheel Copper-Node to Facilitate the Photocatalytic CO₂ Reduction to Ethane", Appl. Catal. B-Environ. 2022, 310, 121320.

9. Reshalaiti Hailili^#, Zhi-Qiang Wang^#, Hongwei Ji, Chuncheng Chen, Xue-Qing Gong*, Hua Sheng* and Jincai Zhao, "Mechanistic Insights into the Photocatalytic Reduction of Nitric Oxide to Nitrogen on Oxygen-Deficient Quasi-Two-Dimensional Bismuth-Based Perovskites", Environ. Sci.-Nano 2022, 9(4), 1453-1465.

8. Wei Wang, Chaoyuan Deng, Shijie Xie, Yangfan Li, Wanyi Zhang, Hua Sheng*, Chuncheng Chen and Jincai Zhao, "Photocatalytic C-C Coupling from Carbon Dioxide Reduction on Copper Oxide with Mixed-Valence Copper(I)/Copper(II)", J. Am. Chem. Soc. 2021, 143(7), 2984-2993. (★Most Cited Publication in JACS from 2020-2021) (★ESI Highly Cited Paper, Hot Paper)

7. Hongna Zhang, Yangfan Li, Jinzhao Wang, Ningning Wu, Hua Sheng*, Chuncheng Chen* and Jincai Zhao, "An Unprecedent Hydride Transfer Pathway for Selective Photocatalytic Reduction of CO₂ to Formic Acid on TiO₂", Appl. Catal. B-Environ. 2021, 284, 119692. 

6. Jose A. Corgejo^#, Hua Sheng^#, Eran Edri^#, Caroline M. Ajo-Franklin* and Heinz Frei*, "Nanoscale Membranes that Chemically Isolate and Electronically Wire Up the Abiotic/Biotic Interface", Nat. Commun. 2018, 9, 2263.

5. Hua Sheng, Myoung Hwan Oh, Wojciech T. Osowiecki, Wooyul Kim, A. Paul Alivisatos and Heinz Frei*, "Carbon Dioxide Dimer Radical Anion as Surface Intermediate of Photoinduced CO₂ Reduction at Aqueous Cu and CdSe Nanoparticle Catalysts by Rapid-Scan FT-IR Spectroscopy", J. Am. Chem. Soc. 2018, 140(12), 4363-4371.

Highlighted: "Dimers on the Way", by Davide Esposito, Nat. Catal. 2018, 1, 234.

4. Hua Sheng and Heinz Frei*, "Direct Observation by Rapid-Scan FT-IR Spectroscopy of Two-Electron-Reduced Intermediate of Tetraza Catalyst [Co^IIN₄H(MeCN)]²⁺ Converting CO₂ to CO", J. Am. Chem. Soc. 2016, 138(31), 9959-9967.

3. Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen* and Jincai Zhao, "Activation of Water in Titanium Dioxide Photocatalysis by Formation of Surface Hydrogen Bonds: An In Situ IR Spectroscopy Study", Angew. Chem. Int. Ed. 2015, 54(20), 5905-5909.

2. Hua Sheng, Hongwei Ji, Wanhong Ma, Chuncheng Chen* and Jincai Zhao, "Direct Four-Electron Reduction of O₂ to H₂O on TiO₂ surface by Pendant Proton Relay", Angew. Chem. Int. Ed. 2013, 52(7), 9686-9690.

1. Hua Sheng, Qin Li, Wanhong Ma, Hongwei Ji, Chuncheng Chen* and Jincai Zhao, "Photocatalytic Degradation of Organic Pollutants on Surface Anionized TiO₂: Common Effect of Anions for High Hole-Availability by Water", Appl. Catal. B-Environ. 2013, 138, 212-218.