课题组长 课题组长

最小化 最大化

               

               盛桦 研究员

             中国科学院化学研究所

             办公室:6号楼1416

             电话:010-82535279

             邮箱:hsheng@iccas.ac.cn

 

个人经历

2018.9起

中国科学院化学研究所   项目研究员

2014.10-2018.5

美国劳伦斯伯克利国家实验室  博士后

2008.9-2014.7

中国科学院化学研究所  硕博连读

2004.9-2008.7

中国科学技术大学 本科0419

招生信息 招生信息

最小化 最大化

2022-2023年度招生名额已满,谢谢关注(更新日期 2022/10/18)

20xx-20xx年度招收硕博连读研究生1名(本科生报考,学制为2+3年)专业方向为环境催化/人工光合成,欢迎化学、材料学、环境科学等相关专业背景的同学联系保送或报考本课题组。

硕博在读 硕博在读

最小化 最大化

博士后

王伟(18级博士,博士:中科院化学所)

博士

李杨凡(18级硕博,本科:山西大学)

盛波(20级博士,硕士:东华大学)

张晚依(19级硕博,本科:中国科学技术大学)

谢杨恩(21级博士,硕士:山东大学)

黄庆(20级硕博,本科:湖北大学)

赵琪(22级博士,硕士:中国建筑材料科学研究院)

硕士

黄星妙(21级硕博,本科:湘潭大学)

张博洋(22级硕博,本科:北京化工大学)

已毕业/出站:

热沙来提·海里里(博士后,去向:北京工业大学)

谢士杰(19级博士)

研究内容 研究内容

最小化 最大化

光催化和环境催化

光催化是利用光能作为驱动力的催化过程,体现了无机或者有机半导体材料在激发态下的反应行为。激发态所诱发的载流子分离使得催化剂在反应过程中存在两种活性物种:还原性的电子与氧化性的空穴,分别驱动还原和氧化半反应的发生。因而也就与热催化过程的单一反应界面不同,光催化反应可以存在两个协同的反应界面。我们的研究兴趣主要在于探究光生载流子在氧化或者还原反应界面上向反应物分子(CO2、H2O、O2以及环境污染物分子)的转移而引发的断键/成键过程,并基于这样的反应机制的研究尝试精细构建复合的催化系统,实现高效的闭合的人工光合成体系(同时实现CO2还原和水氧化)或者双功能化的环境污染物降解。我们目前具体的研究方向包括:

1. 发展二维或者准二维的光催化剂材料,结合原子层沉积(Atomic Layer Deposition)等方法精细构筑复合光催化体系,探究对于铜助催化剂的价态和配位环境的精细调控方法,应用于人工光合成体系(CO2还原)和环境污染物的光催化降解。

2. 发展多时间尺度、多检测模式的原位红外光谱检测系统和方法学,应用于光催化或电催化体系的中间体识别和光谱动力学研究,揭示界面光/电催化反应过程的微观机制。

经费来源 经费来源

最小化 最大化

1. 海外引进高层次人才青年项目,2019.3-2022.3,主持

2. 中科院化学所创新培育项目,"CO2深度还原机理的快速扫描红外光谱研究",2020.1-2023.12,主持

3. 基金委面上项目,"基于新型电子/质子传递膜的双功能的光催化降解污染物体系",22076193, 2021.1-2024.12,主持

4. 国家重点研发计划"变革性技术关键科学问题","面向地外原位资源利用技术的人工光合成关键材料与系统研究",2020YFA0710303, 2020.12-2025.11,课题骨干

5. 中国科学院稳定支持基础研究领域青年团队计划, "高效光解水中的科学问题-光解水过程全时空域原位动态成像研究",YSBR-004,2021.6-2026.6,课题骨干

6. 基金委优秀青年项目,"环境光催化",22222609,2023.1-2025.12,主持

发表论文:2023 发表论文:2023

最小化 最大化

24. Shijie Xie#, Chaoyuan Deng#, Qing Huang, Chuang Zhang*, Chuncheng Chen, Jincai Zhao* and Hua Sheng*, "Facilitated Photocatalytic CO2 Reduction in Aerobic Environment on a Copper-Porphyrin Metal-Organic Framework", Angew. Chem. Int. Ed. 2023, DOI: 10.1002/anie.202216717

23. Jinjie Hao, Shijie Xie, Qing Huang, Zijing Ding, Hua Sheng*, Chuang Zhang* and Jiannian Yao, "Spin-Enhanced C-C Coupling in CO2 Electroreduction with Oxide-Derived Copper", CCS Chem. 2023, DOI: 10.31635/ccschem.022.202202263

2022 2022

最小化 最大化

22. Bo Sheng#, Chaoyuan Deng#, Yangfan Li, Shijie Xie, Zhaohui Wang*, Hua Sheng* and Jincai Zhao, "In-Situ Hydroxylation of Single-Atom Iron Catalyst for Preferential 1O2 Production from H2O2", ACS Catal. 2022, 12(23), 14679-14688.

21. Hailili Reshalaiti*, Hongwei Ji, Kaiwen Wang, Xing'an Dong, Chuncheng Chen, Hua Sheng*, Detlef W. Bahnemann* and Jincai Zhao, "ZnO with Controllable Oxygen Vacancies for Photocatalytic Nitrogen Oxide Removal", ACS Catal. 2022, 12(16), 10004-10017.

20. Shijie Xie#, Yangfan Li#, Bo Sheng, Wanyi Zhang, Wei Wang, Chuncheng Chen, Jikun Li*, Hua Sheng* and Jincai Zhao, "Self-Reconstruction of Paddle-Wheel Copper-Node to Facilitate the Photocatalytic CO2 Reduction to Ethane", Appl. Catal. B-Environ. 2022, 310, 121320.

19. Hailili Reshalaiti#, Zhi-Qiang Wang#, Hongwei Ji, Chuncheng Chen, Xue-Qing Gong*, Hua Sheng* and Jincai Zhao, "Mechanistic Insights into the Photocatalytic Reduction of Nitric Oxide to Nitrogen on Oxygen-Deficient Quasi-Two-Dimensional Bismuth-Based Perovskites", Environ. Sci.-Nano 2022, 9(4), 1453-1465.

18. Tongtong jia, Di Meng, Hongwei Ji, Hua Sheng, Chuncheng Chen, Wenjing Song* and Jincai Zhao, "Visible-Light-Driven Semihydrogenation of Alkynes via Proton Reduction over Carbon Nitride Supportec Nickel", Appl. Catal. B-Environ. 2022, 304, 121004.

17. Wubin Wu, Xiaomeng Guo, Chenghu Dai, Zeyang Zhou, Hongxia Sun, Yeteng Zhong, Hua Sheng, Chuang Zhang* and Jiannian Yao, "Magnetically Boosted Generation of Intracellular Reactive Oxygen Species toward Magneto-Photodynamic Therapy", J. Phys. Chem. B 2022, 126(9), 1895-1903.

2021 2021

最小化 最大化

16. Wei Wang, Chaoyuan Deng, Shijie Xie, Yangfan Li, Wanyi Zhang, Hua Sheng*, Chuncheng Chen and Jincai Zhao, "Photocatalytic C-C Coupling from Carbon Dioxide Reduction on Copper Oxide with Mixed-Valence Copper(I)/Copper(II)", J. Am. Chem. Soc. 2021, 143(7), 2984-2993.

15. Hongna Zhang, Yangfan Li, Jinzhao Wang, Ningning Wu, Hua Sheng*, Chuncheng Chen* and Jincai Zhao, "An Unprecedent Hydride Transfer Pathway for Selective Photocatalytic Reduction of CO2 to Formic Acid on TiO2", Appl. Catal. B-Environ. 2021, 284, 119692.

14. Yukun Zhao, Chaoyuan Deng, Daojian Tang, Liyong Ding, Yuchao Zhang*, Hua Sheng, Hongwei Ji, Wenjing Song, Wanhong Ma, Chuncheng Chen* and Jincai Zhao*, "α-Fe2O3 as a Versatile and Efficient Oxygen Atom Transfer Catalyst in Combination with H2O as the Oxygen Source", Nat. Catal. 20214(8), 684-691.

13. Wubin Wu, Baipeng Yin, Wei Peng, Yukun Zhao, Zeyang Zhou, Hua Sheng, Wanhong Ma and Chuang Zhang*, "Magnetically Modulated Photochemical Reaction Pathways in Anthraquinone Molecules and Aggregates", iScience 2021, 24(5), 102458.

Before 2020 Before 2020

最小化 最大化

12. Liyong Ding, Meng Li, Yukun Zhao, Hongna Zhang, Jinting Shang, Junbo Zhong, Hua Sheng, Chuncheng Chen* and Jincai Zhao, "The Vital Role of Surface Brönsted Acid/Base Sites for the Photocatalytic Formatio of Free OH Radicals", Appl. Catal. B-Environ. 2020, 266, 118634.

11. Yuanxing Fang#, Yun Zheng#, Tao Fang#, Yong Chen, Yaodong Zhu, Qing Liang, Hua Sheng, Zhaosheng Li*, Chuncheng Chen* and Xincheng Wang*, "Photocatalysis: An Overview of Recent Developments and Technological Advancements", Sci. China Chem. 2020, 63, 149-181.

10. Meng Li, Fengxia Bao, Yue Zhang, Hua Sheng, Chuncheng Chen* and Jincai Zhao, "Photochemical Aging of Soot in the Aqueous Phase: Release of Dissolved Black Carbon and the Formation of O2", Environ. Sci. Technol. 2019, 53(21), 149-181.

9. Jose A. Corgejo#, Hua Sheng#, Eran Edri#, Caroline M. Ajo-Franklin* and Heinz Frei*, "Nanoscale Membranes that Chemically Isolate and Electronically Wire Up the Abiotic/Biotic Interface", Nat. Commun. 2018, 9, 2263.

8. Hua Sheng, Myoung Hwan Oh, Wojciech T. Osowiecki, Wooyul Kim, A. Paul Alivisatos and Heinz Frei*, "Carbon Dioxide Dimer Radical Anion as Surface Intermediate of Photoinduced CO2 Reduction at Aqueous Cu and CdSe Nanoparticle Catalysts by Rapid-Scan FT-IR Spectroscopy", J. Am. Chem. Soc. 2018, 140(12), 4363-4371.

7. Hua Sheng and Heinz Frei*, "Direct Observation by Rapid-Scan FT-IR Spectroscopy of Two-Electron-Reduced Intermediate of Tetraza Catalyst [CoIIN4H(MeCN)]2+ Converting CO2 to CO", J. Am. Chem. Soc. 2016, 138(31), 9959-9967.

6. Hua Sheng, Hongna Zhang, Wenjing Song, Hongwei Ji, Wanhong Ma, Chuncheng Chen* and Jincai Zhao, "Activation of Water in Titanium Dioxide Photocatalysis by Formation of Surface Hydrogen Bonds: An In Situ IR Spectroscopy Study", Angew. Chem. Int. Ed. 2015, 54(20), 5905-5909.

5. Wei Chang, Chunyan Sun, Xibin Pang, Hua Sheng, Yue Li, Hongwei Ji, Wenjing Song, Chuncheng Chen, Wanhong Ma* and Jincai Zhao, "Inverse Kinetic Solvent Isotope Effect in TiO2 Photocatalytic Dehalogenation of Non-Adsorbable Aromatic Halides: A Proton-Induced Pathway", Angew. Chem. Int. Ed. 2015, 54(7), 2052-2056.

4. Hua Sheng, Hongwei Ji, Wanhong Ma, Chuncheng Chen* and Jincai Zhao, "Direct Four-Electron Reduction of O2 to H2O on TiO2 surface by Pendant Proton Relay", Angew. Chem. Int. Ed. 2013, 52(7), 9686-9690.

3. Hua Sheng, Qin Li, Wanhong Ma, Hongwei Ji, Chuncheng Chen* and Jincai Zhao, "Photocatalytic Degradation of Organic Pollutants on Surface Anionized TiO2: Common Effect of Anions for High Hole-Availability by Water", Appl. Catal. B-Environ. 2013, 138, 212-218.

2. Changzheng Wu, Zhenpeng Hu, Chengle Wang, Hua Sheng, Jinlong Yang and Yi Xie*, "Hexagonal Cu2SnS3 with Metallic Character: Another Category of Conducting Sulfides", Appl. Phys. Lett. 2007, 91, 143104.

1. Changzheng Wu, Xi Zhu, Chengle Wang, Hua Sheng, Jinlong Yang and Yi Xie*, "Bamboolike Carbon Nitride Nanotubes (C9N5H3): Atomic-Scale Construction, Synthesis and Lithium Battery Applications", Appl. Phys. Lett. 2007, 90, 113116.